課程資訊

PHYSICAL CHEMISTRY (II)

98-2

Chem2006

203 33150

Ceiba 課程網頁
http://ceiba.ntu.edu.tw/982phychemistry2

1. 光電效應與輻射的粒子性(Photoelectron effect and particlelike properties of radiation)
2. 粒子的波動性(Wavelike properties of particles)
3. 海生堡測不準原理(The Heisenberg uncertainty principle)
4. 德布洛意物質波(De Broglie matter wave)
5. 薛丁格方程(The Schrodinger equation)
6. 算子(Operators)
7. 量子力學的基本假設(Basic postulates of quantum mechanics)

1. 一維盒子中的粒子(Particle in a one-dimensional box)
2. 應用到共軛多烯(Application to conjugated polyenes)
3. 粒子在三維盒子的運動(Particle in a three-dimensional box)

1. 古典簡諧振子(The classical harmonic oscillator)
2. 量子簡諧振子(The quantum harmonic oscillator)

1. 類氫原子的薛丁格方程(The Schrödinger equation for hydrogenlike atoms)
2. 類氫原子的本徵函數與機率密度(Eigenfunctions and probability density for hydrogenlike atoms)
3. 類氫原子的軌域角動量(Orbital angular momentum of hydrogenlike aotms)
4. 角動量(Angular momentum)
5. 自旋(Spin)

1. Rayleigh-Schrödinger微擾理論 (Rayleigh-Schrödinger perturbation theory)
2. 變分法(Variation method)

1. 氦原子(Helium atom)
2. 包立不相容原理(Pauli-exclusion principle)
3. 氦的第一激發態(First excited of helium atom
4. 鋰原子(Lithium atom)
5. 週期表與建構原理(The periodic table and the Aufbau principle)
6. 原子的項符號(Atomic term symbols)

1. Born-Oppenheimer近似 (The Born-Oppenheimer approximation)
2. 氫分子離子(The hydrogen molecule ion)
3. 氫分子的分子軌域描述(The molecular orbital description of the hydrogen molecule)
4. 同核雙原子分子的電子組織(Electron configurations of homonuclear diatomic molecules)

2. 光的吸收與發射(Absorption and emission of light)
3. 躍遷機率(Transitional probabilities)
4. 選擇律(Selection rules)

1. 旋轉與振動光譜(Rotational and vibrational spectroscopy)
2. 核運動的薛丁格方程(Schrödinger equation for nuclear motion)
3. 雙原子分子的旋轉光譜(Rotational spectra of diatomic molecules)
4. 雙原子分子的振動光譜(Vibrational spectra of diatomic molecules)
5. 雙原子分子的振動旋轉

Office Hours

Textbook: Physical Chemistry, 4th edition, by Silbey, Alberty, and Bawendi
Reference Book: Quantum Chemistry, 5th edition, by I. N. Levine

(僅供參考)

 No. 項目 百分比 說明 1. 作業 20% 2. 平時成績 10% 包含小考與上課發問情形 3. 期中考 40% 三次期中考取成績最高兩次平均。期中考日期為 3/27, 4/24, 5/22. 4. 期末考 30%

 課程進度
 週次 日期 單元主題 第1週 2/23,2/26 Why Quantum Mechanics? The Heisenberg Uncertainty Principle, The Schrödinger Equation 第2週 3/02,3/05 Operators, The Superposition Principle & Expectation Values, Measurement 第3週 3/09,3/12 Particle in a One-Dimensional Box, Particle in a Three-Dimensional Box, Tunneling 第4週 3/16,3/19 Quantum Harmonic Oscillator 第5週 3/23,3/26 Postulates of Quantum Mechanics, Dirac Notation, Harmonic Oscillator Revisited, Direct Numerical Solution to the Schrödinger Eq., Superposition of Vibrational States & Wave Packets 第6週 3/30,4/02 Angular Momentum & The Rigid Rotor, The Heisenberg Uncertainty Principle Revisited 第7週 4/09 The Schrödinger Equation for Hydrogen-like Atoms 第8週 4/13,4/16 Hydrogen-like Orbitals, Orbital Angular Momentum & Electron Spin 第9週 4/20,4/23 Approximation Methods: Non-degenerate Perturbation Theory & Variational Method 第10週 4/27,4/30 Helium Atom, Pauli Exclusion Principle, Slater Determinant, Many-Electron Problems: Hartree-Fock Self-consistent Field Method 第11週 5/04,5/07 The Born-Oppenheimer Approximation, The Hydrogen Molecule Ion, Electronic Structure of Many-electron Molecules: Molecular Orbital Theory 第12週 5/11,5/14 Valence Bond Method, Huckel Theory, Computational Chemistry 第13週 5/18,5/21 The Interaction between Molecules and Radiation, Transition Probabilities, Selection Rules 第14週 5/25,5/28 Rotational & Vibrational Spectroscopy of Molecules 第15週 6/01,6/04 Electronic Spectroscopy of Diatomic Molecules, Franck-Condon Principle 第16週 6/08 Electronic & Vibrational Relaxation, Fluorescence & Phosphorescence 第17週 6/15,6/18 Magnetic Resonance Spectroscopy