課程資訊
課程名稱
物理化學一-熱力學
Physical Chemistry (Ⅰ)-Thermodynamics 
開課學期
103-1 
授課對象
理學院  化學系  
授課教師
鄭原忠 
課號
Chem3030 
課程識別碼
203 33160 
班次
 
學分
全/半年
半年 
必/選修
必修 
上課時間
星期三2(9:10~10:00)星期五3,4(10:20~12:10) 
上課地點
化210室化210室 
備註
1.先修普化甲/普物甲/微積分甲。2.詳選課須知。本課程將全程錄影並置於臺大開放式課程網站http://ocw.aca.ntu.edu.tw/ntu-ocw/
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限:80人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1031Chem3030_ 
課程簡介影片
 
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課程概述

This course aims to provide a rigorous presentation of thermodynamics principles, with emphases on the application of mathematical methods to the study of the spontaneity of processes, chemical reactions, and chemical energy. In addition to thermodynamics description of chemical equilibrium phenomena that form the basis of macroscopic chemical principles, connections between microscopic pictures (quantum mechanics and statistical mechanics) and bulk properties will also be highlighted.
Planned topics: SAB Chapters 1-8, 16.
 

課程目標
Establish important thermodynamics concepts and their microscopic interpretations. 
課程要求
待補 
預期每週課後學習時數
 
Office Hours
每週五 15:30~17:20
每週三 08:10~09:00 備註: 助教時間 
參考書目
Textbook:
Physical Chemistry, 4th Edition by Robert J. Silbey, Robert A. Alberty, and
Moungi G. Bawendi, Wiley [SAB].

Recommended reference book:
Statistical Mechanics by Donald Allan McQuarrie, University Science Books
[MQ].
 
指定閱讀
Textbook:
• Physical Chemistry, 4th Edition by Robert J. Silbey, Robert A. Alberty, and Moungi G. Bawendi, Wiley [SAB].
Recommended reference book:
• Statistical Mechanics by Donald Allan McQuarrie, University Science Books [MQ]. 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
Homework & quizzes 
30% 
 
2. 
Midterm exams 
40% 
 
3. 
Final exam 
30% 
 
 
課程進度
週次
日期
單元主題
第1週
9/17,9/19  Notions of Thermodynamics, Zeroth Law of
Thermodynamics. SAB Ch.1 
第2週
9/24,9/26  Equations of State, Critical phenomena. SAB Ch.1, Ch.2 
第3週
10/01,10/03  First Law of Thermodynamics, Reversibility,
Spontaneous Process. SAB Ch.2 
第4週
10/08,10/10  Adiabatic Processes, Joule-Thomson effect, Entropy. SAB Ch.3 
第5週
10/15,10/17  Entropy, Second Law of Thermodynamics, Entropy Variation Principle, Entropy of Mixing. SAB Ch.3 
第6週
10/22,10/24  Carnot cycle, Third Law of Thermodynamics. SAB Ch.3  
第8週
11/05,11/07  Legendre Transformation, Thermodynamic Potentials, Fundamental Equations of Thermodynamics, Chemical Potential. SAB Ch.4 
第9週
11/12,11/14  Fugacity & Activity, Gibbs-Duhem Equation, Reaction Gibbs Free Energy. SAB Ch.5 
第10週
11/19,11/21  Chemical Equilibrium, Phase transition. SAB Ch.5 
第11週
11/26,11/28  Claperyon Equation, Vapor-Liquid Equilibrium of Binary Mixtures. Ch.6 
第13週
12/10,12/12  Phase Diagram of Binary Systems, Colligative Properties. SAB Ch.6 
第14週
12/17,12/19  Electrochemical Equilibrium. SAB Ch.7 
第15週
12/24,12/26, 12/27  Electrochemical Equilibrium, Thermodynamics of Biochemical Reactions. SAB Ch.8 
第16週
12/31  Thermodynamics of Biochemical Reactions. SAB Ch.8 
第17週
1/07,1/09  Introduction to Statistical Mechanics. SAB Ch.16 
第18週
TBA  Final Exam 
第7-1週
10/29  Fundamental Thermodynamic Equations for the Internal Energy. SAB Ch.4 
第7-2週
10/31  Mid-term Exam (Friday) 
第12-1週
12/03  Mixcible Binary Systems 
第12-2週
12/05  Mid-term Exam (Friday)