課程資訊
課程名稱
物理化學一-熱力學
Physical Chemistry (Ⅰ)-Thermodynamics 
開課學期
102-1 
授課對象
理學院  化學系  
授課教師
鄭原忠 
課號
Chem3030 
課程識別碼
203 33160 
班次
 
學分
全/半年
半年 
必/選修
必修 
上課時間
星期三2(9:10~10:00)星期五3,4(10:20~12:10) 
上課地點
化210室化210室 
備註
1.先修普化甲/普物甲/微積分甲。2.詳選課須知。
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限:80人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1021Chem3030 
課程簡介影片
 
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課程概述

This course aims to provide a rigorous presentation of thermodynamics principles, with emphases on the application of mathematical methods to the study of the spontaneity of processes, chemical reactions, and chemical energy. In addition to thermodynamics description of chemical equilibrium phenomena that form the basis of macroscopic chemical principles, connections between microscopic pictures (quantum mechanics and statistical mechanics) and bulk properties will also be highlighted.
Planned topics: SAB Chapters 1-8, 16.
 

課程目標
Establish important thermodynamics concepts and their microscopic interpretations. 
課程要求
 
預期每週課後學習時數
 
Office Hours
每週二 16:00~17:00 
參考書目
Textbook:
Physical Chemistry, 4th Edition by Robert J. Silbey, Robert A. Alberty, and Moungi G. Bawendi, Wiley
[SAB].

Recommended reference book:
Statistical Mechanics by Donald Allan McQuarrie, University Science Books [MQ].
 
指定閱讀
 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
Homework & quizzes 
30% 
 
2. 
Midterm 
40% 
Two mid-term exams, 20% each. 
3. 
Final 
30% 
 
 
課程進度
週次
日期
單元主題
第1週
9/11,9/13  Notions of Thermodynamics, Zeroth Law of Thermodynamics (SAB Ch. 1) 
第2週
9/18  Equations of State (SAB Ch. 1) 
第3週
9/25,9/27  First Law of Thermodynamics (SAB Ch. 2) 
第4週
10/02,10/04  Reversibility, Spontaneous Process, Second
Law of Thermodynamics (SAB Ch. 3) 
第5週
10/09,10/11  Carnot cycle, Third Law of Thermodynamics (SAB Ch. 3) 
第6週
10/16,10/18  Free Energy, Fundamental Equations of
Thermodynamics (SAB Ch. 4) 
第7週
10/23,10/25  Fundamental Equations of Thermodynamics (SAB Ch. 4),

Mid-term Exam (Friday) 
第8週
10/30,11/01  Chemical Equilibrium (SAB Ch. 5) 
第9週
11/06,11/08  Chemical Equilibrium (SAB Ch. 5), Phase transition (SAB Ch. 6) 
第10週
11/13  11/15 校慶停課; Phase Equilibrium (SAB Ch. 6) 
第11週
11/20,11/22  Phase Transition, Colligative Properties (SAB Ch. 6) 
第12週
11/27,11/29  Non-ideal solutions, activity of electrolytes, Debye-Huckel theory (SAB Ch. 7) 
第13週
12/06  12/4 老師出國停課; Mid-term Exam (Friday) 
第14週
12/11,12/13  Electrochemical Equilibrium (SAB Ch. 7); Thermodynamics of Biochemical Reactions (SAB Ch. 8) 
第15週
12/18,12/20  Thermodynamics of Biochemical Reactions (SAB Ch. 8) 
第16週
12/25,12/27  Thermodynamics of Biochemical Reactions (SAB Ch. 8) 
第17週
1/03  Thermodynamics of Biochemical Reactions (SAB Ch. 8)