課程資訊
課程名稱
物理化學一-熱力學
Physical Chemistry (Ⅰ)-Thermodynamics 
開課學期
101-1 
授課對象
理學院  化學系  
授課教師
陸駿逸 
課號
Chem3030 
課程識別碼
203 33160 
班次
 
學分
全/半年
半年 
必/選修
必修 
上課時間
星期三2(9:10~10:00)星期五3,4(10:20~12:10) 
上課地點
化210室化210室 
備註
1.先修普化甲/普物甲/微積分甲。2.詳選課須知。
限學士班三年級以上 且 限本系所學生(含輔系、雙修生)
總人數上限:80人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1011PChem1 
課程簡介影片
 
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課程概述

This course will cover the following topics: basic concepts of thermodynamics and statistical thermodynamics, chemical equilibrium and electrochemical equilibrium, phase transition, diffusion.

The course will contain the following topics. The materials with * will depend on the available time.

Chapters 1-7,
1. temperature, equations of state
2. 1st law,
3. 2nd and third laws,
4. Fundamental equation of thermodynamics,
5. chemical equilibrium,

16. Statistical Mechanics (ideal gas, internal degrees of freedom, solid, Debye model)
Statistical Mechanics of Van der Waals liquid

6. phase equilibrium,
7. electrochemistry and Debye Huckel, electrophoresis

* 21. Macromolecules (Rg, freely rotation model, excluded volume, coil-globule transition)
* 20. Liquid (diffusion) (Langevin equation, diffusion equation, dynamic light scattering)
 

課程目標
Establish important thermodynamics concepts and their microscopic interpretations. 
課程要求
Home work + one midterm and the final exams. 
預期每週課後學習時數
 
Office Hours
 
參考書目
To come. 
指定閱讀
Physical Chemistry
by Robert J. Silbey, Robert A. Alberty and Moungi G. Bawendi (2004)
 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
home work 
40% 
 
2. 
midterm exam 
30% 
 
3. 
final exam 
30% 
 
 
課程進度
週次
日期
單元主題
第1週
9/12,9/14  Zeroth law of thermodynamics, equation of state
習題 1.7, 1.8, 1.9, 1.10, 1.11, 1.17, 1.18, 1.B, 1.C (9/24 交) 
第2週
9/19,9/21  van der Waals' equation, number of variables, Euler's theorem, barometric formula, work, 1st law, exact differential  
第3週
9/26,9/28  more works, reversible path, Cv, Cp, ideal gas, adiabatic process, Joule-Thomson expansion, enthalpy of reaction 
第4週
10/03,10/05  Carnot cycle, 2nd laws (Clausius,Kelvin), Carnot theorem, thermodynamic temperature scale, Clausius inequality 
第5週
10/10,10/12  entropy, Caratheodory theory 
第6週
10/17,10/19  ideal gas entropy, Cv of solid, entropy of mixing, Gibbs' paradox, Nernst's theorem, third law of thermodynamics  
第8週
10/31,11/02  U, A, G min, Gibbs-Helmholtz equation, Gibbs-Duhem equation, Maxwell relations, 習題: 4.2,4.16, 4.17, 4.21,4.24, 4.29, 4.30, 4.32, 4.38  
第10週
11/14,11/16  Chemical equilibrium, K, Boltzmann entropy formula 習題:5.5, 5.17, 5.23, 5.27, 5.38, 5.72, 5.74, 5.80 
第11週
11/21,11/23  microcanonical ensemble, ideal gas entropy formula 
第12週
11/28,11/30  Boltzmann factor, Equipartition, Eistein model of solid 習題:Callen 15.2-1, 15.2-3 
第13週
12/05,12/07  Einstein model of solid, crystal vibration modes, Debye model 
第14週
12/12,12/14  Debye model (correcting the errors in the previous notes), (The A in problem 15.2-3 is a constant.) 
第15週
12/19,12/21  partition function, Gibbs' entropy formula, ideal gas (again), van der Waals' model, the meaning of a & b, the free energy of coexisting two phases 
第16週
12/26,12/28  Clapeyron equation, Raoult's law, ideal solution
習題:6.2, 6.8, 6.26, 6.29, 6.B 
第17週
1/02,1/04  phase diagrams, colligative properties, surface tension, Kelvin equation, Wulff construction of crystal shape (Ref. by Ringe, and DebyeHuckel are not the exam materials.)