台灣大學107學年第2學期
開課系所： 化學系
課程名稱： 物理化學下
授課對象： 農化系
授課老師：陳逸聰教授


107學年下學期　物理化學(二) 課程大綱　陳逸聰 教授

【Chapter 7. Introduction to quantum theory】

Topic 7A The origins of quantum mechanics
7A.1 Energy quantization
7A.2 Wave-particle duality
Topic 7B Dynamics of microscopic systems
7B.1 The Schrodinger equation
7B.2 The Born interpretation of the wavefunction
7B.3 The probability density
Topic 7C The principles of quantum theory
7C.1 Operators
7C.2 Superpositions and expectation values
7C.3 The uncertainty principle
7C.4 The postulates of quantum mechanics

【Chapter 8. The quantum theory of motion】

Topic 8A Translation
8A.1 Free motion in one dimension
8A.2 Confined motion in one dimension
8A.3 Confined motion in two or more dimensions
8A.4 Tunneling
Topic 8B Vibrational motion
8B.1 The harmonic oscillator
8B.2 The properties of oscillators
Topic 8C Rotational motion
8C.1 Rotation in two dimensions
8C.2 Rotation in three dimensions

【Chapter 9. Atomic structure and spectra】

Topic 9A Hydrogenic atoms
9A.1 The structure of hydrogenic atoms
9A.2 Atomic orbitals and their energies
Topic 9B Many-electron atoms
9B.1 The orbital approximation
9B.2 The building-up principle
9B.3 Self-consistent field orbitals
Topic 9C Atomic spectra
9C.1 The spectra of hydrogenic atoms
9C.2 The spectra of complex atoms

【Chapter 10. Molecular structure】

Topic 10A Valence-bond theory
10A.1 Diatomic molecules
10A.2 Polyatomic molecules
Topic 10B Principles of molecular orbital theory
10B.1 Linear combinations of atomic orbitals
10B.2 Orbital notation
Topic 10C Homonuclear diatomic molecules
10C.1 Electron configurations
10C.2 Photoelectron spectroscopy
Topic 10D Heteronuclear diatomic molecules
10D.1 Polar bonds
10D.2 The variation principle
Topic 10E Polyatomic molecules
10E.l The Hückel approximation
10E.2 Applications
10E.3 Computational chemistry

【CHAPTER 12. Rotational and vibrational spectra 】
(Vibrational spectra will be emphasized in this chapter.)

Topic 12A General features of molecular spectroscopy
12A.1 The absorption and emission of radiation
12A.2 Spectral linewidths
12A.3 Experimental techniques
Topic 12D Vibrational spectroscopy of diatomic molecules
12D.1 Vibrational motion
12D.2 Infrared spectroscopy
12D.3 Anharmonicity
12D.5 Vibrational Raman spectra
Topic 12E Vibrational spectroscopy of polyatomic molecules
12E.1 Normal modes
12E.2 Infrared absorption spectra
12E.3 Vibrational Raman spectra
12E.4 Symmetry aspects of molecular vibrations

【CHAPTER 13. Electronic transitions】
(if time is available)

Topic 13A Electronic spectra
13A.1 Diatomic molecules
13A.2 Polyatomic molecules
Topic 13B Decay of excited states
13B.1 Fluorescence and phosphorescence
13B.2 Dissociation and predissociation
Topic 13C Lasers
13C.1 Population inversion
13C.2 Cavity and mode characteristics