課程資訊
課程名稱
高等分析化學專論一
Discussion in Advanced Analytical Chemistry (Ⅰ) 
開課學期
102-1 
授課對象
理學院  化學所化學組  
授課教師
張哲政 
課號
Chem8025 
課程識別碼
223 D1130 
班次
 
學分
全/半年
半年 
必/選修
必修 
上課時間
星期二3,4(10:20~12:10)星期五2(9:10~10:00) 
上課地點
 
備註
本課程中文授課,使用英文教科書。上課教室:化121。
限博士班
總人數上限:20人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1021daacc 
課程簡介影片
 
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課程概述

Overview: An introduction to the basic theory and practice underlying important electroanalytical methods and electron spectroscopy as well as their applications.
This course is presented in a lecture/discussion format. The content of the course includes Nanoscale electronic switch, solute ion conductance, ion mobility, electrical conductivity, transport numbers, thermodynamics of electrochemical cells, galvanic couple, exchange current density, electrode process, electrode polarization, activation polarization, concentration polarization, resistance polarization, Helmholtz double layer, Guoy-Chapman layer, Stern layer, liquid junction potential, overpotential, anodic dissolution of metals, ion selective electrodes, electrochemical instrumentation, electrolysis, potentiometry, Nicolsky equation, photocatalysis, photoelectron emission, coulometry, amperometry, chronoamperometry, chronocoulometry, electrogravimetry, electrochemical step edge decoration, nanowire electrooxidation, polarographic measurement, voltammetric measurement, supporting electrolyte, microelectrode, potential range, reversible electrode reaction, Faraday current, charging current, mass transfer, Faraday’s Law, instantaneous current, limiting current, Cottrell equation, hydrodynamic voltammetry, stationary solution voltammetry, cyclic voltammetry, Randles-Sevcik equation, differential pulse voltammetry, electrochemical impedance spectroscopy, photoelectron spectroscopy, Auger spectroscopy, scanning Auger microscopy, electron probe microanalysis, spectroscopic instrumentation, redox probe microscopy.  

課程目標
This course provides students with an in-depth understanding about the background theory and operation principles of different analytical methods that employ electrons. The specific objectives of the course are to help students
-to become familiar with the various electroanalytical and electron beam/spectroscopic methods currently available
-to develop an understanding of the theories upon which the principles of the electroanalytical and electron beam/spectroscopic procedures are based
-to understand the correlations of chemical analysis concepts and of various controllable and measurable quantities
-to learn how different analytical methods that employ electrons are used to analyze samples
-to appreciate the development of electrochemical and electron analytical methods in nanoscience and nanotechnology
-to understand the basic strengths and limitations of each electroanalytical and electron beam/spectroscopic method
-to learn to apply chemical equilibria, stoichiometry, thermodynamics and kinetics to solve analytical problems using electroanalytical and electron beam/spectroscopic methods
 
課程要求
Listening to lectures and participatory attendance are essential to successful mastery of course material. Although the attendance will not be monitored daily, it is suggested that you do not take this course if you cannot come to the class. Handouts are given only in the current class session. Taking notes during lectures is an important skill for students’ life-long educational careers. Students should thus keep class notes. Photography and videotaping of any form are not allowed in the classroom. Cell phone use is also forbidden. 
預期每週課後學習時數
 
Office Hours
每週五 10:00~12:00 備註: The session starts right after the regular class and ends when the last student leaves. 
指定閱讀
Optional Text :
Allen J. Bard, L. R. Faulkner, Electrochemical Methods – Fundamentals and Applications, John Wiley & Sons
Douglas A. Skoog, F. James Holler, Stanley R. Crouch, Principles of Instrumental Analysis (6th Edition), Thomson Books/Cole
 
參考書目
1. Wikipedia
2. Daniel C. Harris, Quantitative Chemical Analysis, 8th Ed., W.H. Freeman and Company 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
Final Exam 
60% 
The exams are primarily problems and short essays, not true-false or multiple choice. They will emphasize the course objectives of understanding the fundamental theory and concepts, operation principles, design, applications, strengths, and limitations of the electrochemical and electron analytical methods introduced. The final test is a comprehensive exam and will require you to integrate the class material in a meaningful way. Calculators used in the exam cannot contain any dictionary function. Cell phones and any other communication devices should be kept away from the exam. Anyone who only sits in the class is not allowed to take the midterm or the final. Make-up exams will not be permitted to those who miss the midterms or the final. Do not take this course if you have a class/activity schedule that is in some way in conflict with our class and exam schedules. Students should present records of clinic visits for missing the exam due to illness. The NTU policies on cheating will be enforced. 
2. 
Midterm Exam 
40% 
The exams are primarily problems and short essays, not true-false or multiple choice. They will emphasize the course objectives of understanding the fundamental theory and concepts, operation principles, design, applications, strengths, and limitations of the electrochemical and electron analytical methods introduced. Calculators used in the exam cannot contain any dictionary function. Cell phones and any other communication devices should be kept away from the exam. Anyone who only sits in the class is not allowed to take the midterm or the final. Make-up exams will not be permitted to those who miss the midterms or the final. Do not take this course if you have a class/activity schedule that is in some way in conflict with our class and exam schedules. Students should present records of clinic visits for missing the exam due to illness. The NTU policies on cheating will be enforced. 
 
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