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課程名稱 |
高等無機化學專論一
DISCUSSION IN ADVANCED INORGANIC CHEMISTRY (I) |
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開課學期 |
99-1 |
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授課對象 |
理學院 化學所化學組 |
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授課教師 |
王 瑜 |
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課號 |
Chem8029 |
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課程識別碼 |
223ED1410 |
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班次 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期二2(9:10~10:00)星期四3,4(10:20~12:10) |
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上課地點 |
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備註 |
本課程以英語授課。本課程以英語授課。上課教室：化121。
限博士班
總人數上限：20人 |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
Outline
I. Symmetry & Bonding
Atomic orbitals: H-like; many electron; spectra terms
Symmetry elements; Point groups; Molecular geometries
Symmetry operator; Character table; Representation; Group theory
Applications on molecular orbitals
hybridization orbital
MO of diatomic molecule
MO of Hn
MO of delocalized pi orbitals
MO of AHn
MO of AXn
Applications on Molecular vibrations
Walsh diagram
Orbital E vs Geometry change
II. Transition Metal Chemistry
Electronic Configuration, Spectroscopy, Magnetism
Coordination Chemistry, Tanabe and Sugano Diagrams
Bonding, Structures, Reactivity & Reaction Mechanisms
III. Main Group Chemistry
Ionic & Covalent Bond, Chemical Forces, H-Bonding & Acid-Base Chemistry
Structures & Reactivity
Supramolecular Chemistry & Organometallic Chemistry
A Brief Introduction on Modern Development
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課程目標 |
Bonding, Structure, Reactivity, Mechanism, and Applications of Inorganic Compounds |
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課程要求 |
先修科目 Pre-requistes 1. General Chemistry 2. Inorganic Chemistry, Undergraduate Level
本課程以英語授課。外系所學生選修需經授課教師同意。與劉陵崗教授合開。
限碩士班以上。總人數上限：50人
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預期每週課前或/與課後學習時數 |
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Office Hours |
另約時間 |
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指定閱讀 |
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參考書目 |
1. F. Albert Cotton; "Chemical Applications of Group Theory"; Wiley-
Interscience; 1990; 3rd Edition.
2. James E. Huheey, Ellen A. Keiter, Richard L. Keiter; "Inorganic Chemistry:
Principles of Structure and Reactivity"; Benjamin Cummings; 1997; 4th Edition.
3. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Murillo, Manfred Bochmann,
Russel Grimes; "Advanced Inorganic Chemistry"; Wiley- Interscience; 1999; 6th
Edition.
4. Gary L. Miessler, Donald A. Tarr; "Inorganic Chemistry"; Pearson Prentice
Hall; 2004; 3rd Edition.
5.Yves Jean; Francois Volatron; Jeremy Burdett;“An Introduction to Molecular Orbitals”Oxford. |
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
3 Examinations |
75% |
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2. |
Assignments, Homework, Term Paper and/or Presentation |
25% |
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- 本校建議 A+ 比例上限為 20% ，非強制規定，授課教師可依課程要求調整，建議必修課程參考。
- 本校採用等第制評定成績，學生成績評量辦法中的百分制分數區間與單科成績對照表僅供參考，授課教師可依等第定義調整分數區間。詳見學習評量專區 (連結)。
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週次 |
日期 |
單元主題 |
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第1週 |
9/15,9/17 |
Atomic orbitals: H-like; many electron; spectra terms
Symmetry elements; Point groups; Molecular geometries
Symmetry operator; Character table; Representation; Group theory |
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第2週 |
9/22,9/24 |
Applications on molecular orbitals:
hybridization orbital;
MO of diatomic molecule;
MO of Hn;
MO of delocalized pi orbitals;
MO of AHn;
MO of AXn; |
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第3週 |
9/29,10/01 |
Applications on molecular orbitals:
hybridization orbital;
MO of diatomic molecule;
MO of Hn;
MO of delocalized pi orbitals;
MO of AHn;
MO of AXn; |
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第4週 |
10/06,10/08 |
Applications on Molecular vibrations |
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第5週 |
10/13,10/15 |
Walsh diagram:
Orbital E vs Geometry change |
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第6週 |
10/20,10/22 |
First Exam(10/22) |
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第7週 |
10/27,10/29 |
II. Transition Metal Chemistry |
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第8週 |
11/03,11/05 |
Electronic Configuration, Spectroscopy, Magnetism |
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第9週 |
11/10,11/12 |
Coordination Chemistry |
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第10週 |
11/17,11/19 |
Bonding, Structures |
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第11週 |
11/24,11/26 |
Reactivity & Reaction Mechanisms |
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第12週 |
12/01,12/03 |
2nd Exam |
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第13週 |
12/08,12/10 |
III. Main Group Chemistry
Ionic & Covalent Bond, Chemical Forces, H-Bonding & Acid-Base Chemistry
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第14週 |
12/15,12/17 |
Structures & Reactivity |
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第15週 |
12/22,12/24 |
Supramolecular Chemistry & Organometallic Chemistry |
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第16週 |
12/29,12/31 |
A Brief Introduction on Modern Development |
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第17週 |
1/05,1/07 |
Final Exam |
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