課程大綱

課程資訊

課程名稱

有機金屬化學
Organometallic Chemistry

開課學期

107-2

授課對象

理學院化學系

授課教師

江建文

課號

Chem5112

課程識別碼

223 U0950

班次

學分

3.0

全/半年

半年

必/選修

選修

上課時間

星期二6(13:20~14:10)星期四6,7(13:20~15:10)

上課地點

化217化217

備註

本課程中文授課,使用英文教科書。
限學士班三年級以上且限本系所學生(含輔系、雙修生)
總人數上限：60人

Ceiba 課程網頁

http://ceiba.ntu.edu.tw/1072Chem5112_

課程簡介影片

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課程大綱

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課程概述

We will start to introduce different classes of ligands. The process of ligand interacts with metal. Last section will be introduction of organic reactions involving organometallic compounds.

課程目標

A course to give students understand what is organometallic chemistry and its applications.

課程要求

Understanding the basic of organometallic chemistry

預期每週課前或/與課後學習時數

Office Hours

另約時間備註： email lecturer at anytime and face to face conversation fixed by email.

指定閱讀

The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill

參考書目

The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill

評量方式
(僅供參考)

No.	項目	百分比	說明
1.	Midterm exam	30%	KV will be in charge
2.	Report	20%	KV will be in charge
3.	Final exam	50%	Professor Hiroshi Nakazawa will be in charge

本校建議 A+ 比例上限為 20% ，非強制規定，授課教師可依課程要求調整，建議必修課程參考。
本校採用等第制評定成績，學生成績評量辦法中的百分制分數區間與單科成績對照表僅供參考，授課教師可依等第定義調整分數區間。詳見學習評量專區 (連結)。

課程進度

週次	日期	單元主題
第1週	2/19,2/21	By KV Introduction: What is organometallics? EAN rule and 18 electron rule
第2週	2/26,2/28	By KV Inorganic ligands • Carbonyl • Phosphines • Other related ligands 2/28 Public Holiday - No Class
第3週	3/05,3/07	By KV Alkyl, hydride and related monohapto ligands • Alkyls, aryls, vinyl, alkynyl, etc • Hydride Updated Syllabus Experiments and Techniques in Organometallic Chemistry
第4週	3/12,3/14	By KV Updated power point for lecture 3 Carbenes and carbynes • Carbenes • Carbynes Ligands employing p-electrons • Alkene, alkyne, diene and benzene • Metallocenes • Allyl, (cyclo)pentadienyl
第5週	3/19,3/21	By KV Organometallic Complexes Viewed from Molecular Orbital Theory
第6週	3/26,3/28	By KV Lab demonstration
第7週	4/02,4/04	Public Holidays- NO Class
第8週	4/09,4/11	By KV Organometallic Complexes Viewed from Molecular Orbital Theory
第9週	4/16,4/18	Mid Term 18/4
第10週	4/23,4/25	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第11週	4/30,5/02	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第12週	5/07,5/09	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第13週	5/14,5/16	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第14週	5/21,5/23	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第15週	5/28,5/30	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第16週	6/04,6/06	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第17週	6/11,6/13	Final Exam 13/6