課程名稱 |
高等物理化學一 Advanced Physical Chemistry (Ⅰ) (Chem. Thermodynamics)(Ⅰ) |
開課學期 |
110-1 |
授課對象 |
工學院 分子科學與技術國際研究生博士學位學程 |
授課教師 |
鄭原忠 |
課號 |
Chem7031 |
課程識別碼 |
223EM1310 |
班次 |
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學分 |
3.0 |
全/半年 |
半年 |
必/選修 |
選修 |
上課時間 |
星期二6,7(13:20~15:10)星期四2(9:10~10:00) |
上課地點 |
化210室化210室 |
備註 |
本課程以英語授課。外系所學生選修需經授課教師同意。
本班英文授課。 限碩士班以上 且 限本系所學生(含輔系、雙修生) 總人數上限:30人 |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
課程大綱
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課程概述 |
This course covers the principles and methods of equilibrium statistical mechanics for applications to chemical physics problems. The lectures will be divided into three parts: a short review of thermodynamics principles, the concepts of ensemble theory and the applications to gas, liquid, solution and solid systems. The final part will introduce the phase transition and the theory of Brownian motion.
Planned topics: laws of thermodynamics, thermal equilibrium and temperature, ensemble theory, entropy, non-interacting systems (gas and solid), chemical equilibrium, imperfect gases, classical liquids, ionic and non-ionic solutions, Ising models. Langevin equation and Brownian motion. |
課程目標 |
This course aims to introduce basic concepts of equilibrium statistical mechanics for physical chemistry in the graduate level. |
課程要求 |
待補 |
預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
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參考書目 |
Textbooks:
Introduction to Modern Statistical Mechanics, David Chandler, Oxford University Press.
Statistical Physics of Particles, Tehran Kardar, Cambridge University Press.
References:
Statistical Mechanics, Donald Allan McQuarrie, University Science Books; 2nd edition. |
評量方式 (僅供參考) |
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週次 |
日期 |
單元主題 |
Week 1 |
9/23 |
Notions of statistical thermodynamics |
Week 2 |
9/28, 9/30 |
Laws of thermodynamics, Fundamental equations of thermodynamics |
Week 3 |
10/5, 10/7 |
Equilibrium and stability, Statistical methods and ensemble |
Week 4 |
10/12, 10/14 |
The canonical ensemble, Entropy and free energy functions |
Week 5 |
10/19, 10/21 |
Photon gas, harmonic oscillators |
Week 6 |
10/26, 10/28 |
10/26: Mid-term Exam
10/28: Statistics of particles |
Week 7 |
11/2, 11/4 |
Ideal polyatomic gas |
Week 8 |
11/9, 11/11 |
Chemical equilibrium |
Week 9 |
11/2, 11/4 |
Ising model, Phase transitions |
Week 10 |
11/23, 11/25 |
Imperfect gas |
Week 11 |
11/30, 12/2 |
Liquid theory |
Week 12 |
12/7, 12/9 |
Electrolytes |
Week 13 |
12/14, 12/16 |
Brownian motion |
Week 14 |
12/21 |
Final Exam |
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