課程名稱 |
有機金屬化學 Organometallic Chemistry |
開課學期 |
107-2 |
授課對象 |
理學院 化學系 |
授課教師 |
江建文 |
課號 |
Chem5112 |
課程識別碼 |
223 U0950 |
班次 |
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學分 |
3.0 |
全/半年 |
半年 |
必/選修 |
選修 |
上課時間 |
星期二6(13:20~14:10)星期四6,7(13:20~15:10) |
上課地點 |
化217化217 |
備註 |
本課程中文授課,使用英文教科書。 限學士班三年級以上 且 限本系所學生(含輔系、雙修生) 總人數上限:60人 |
Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1072Chem5112_ |
課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
課程大綱
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課程概述 |
We will start to introduce different classes of ligands. The process of ligand interacts with metal. Last section will be introduction of organic reactions involving organometallic compounds. |
課程目標 |
A course to give students understand what is organometallic chemistry and its applications. |
課程要求 |
Understanding the basic of organometallic chemistry |
預期每週課後學習時數 |
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Office Hours |
另約時間 備註: email lecturer at anytime and face to face conversation fixed by
email. |
指定閱讀 |
The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill
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參考書目 |
The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill |
評量方式 (僅供參考) |
No. |
項目 |
百分比 |
說明 |
1. |
Midterm exam |
30% |
KV will be in charge |
2. |
Report |
20% |
KV will be in charge |
3. |
Final exam |
50% |
Professor Hiroshi Nakazawa will be in charge |
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週次 |
日期 |
單元主題 |
第1週 |
2/19,2/21 |
By KV
Introduction: What is organometallics?
EAN rule and 18 electron rule
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第2週 |
2/26,2/28 |
By KV
Inorganic ligands
• Carbonyl
• Phosphines
• Other related ligands
2/28 Public Holiday - No Class
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第3週 |
3/05,3/07 |
By KV
Alkyl, hydride and related monohapto ligands
• Alkyls, aryls, vinyl, alkynyl, etc
• Hydride
Updated Syllabus
Experiments and Techniques in Organometallic Chemistry |
第4週 |
3/12,3/14 |
By KV
Updated power point for lecture 3
Carbenes and carbynes
• Carbenes
• Carbynes
Ligands employing p-electrons
• Alkene, alkyne, diene and benzene
• Metallocenes
• Allyl, (cyclo)pentadienyl
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第5週 |
3/19,3/21 |
By KV
Organometallic Complexes Viewed from Molecular Orbital Theory |
第6週 |
3/26,3/28 |
By KV
Lab demonstration |
第7週 |
4/02,4/04 |
Public Holidays- NO Class |
第8週 |
4/09,4/11 |
By KV
Organometallic Complexes Viewed from Molecular Orbital Theory |
第9週 |
4/16,4/18 |
Mid Term 18/4 |
第10週 |
4/23,4/25 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第11週 |
4/30,5/02 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第12週 |
5/07,5/09 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第13週 |
5/14,5/16 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第14週 |
5/21,5/23 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第15週 |
5/28,5/30 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第16週 |
6/04,6/06 |
By Professor Hiroshi Nakazawa
• Oxidative Addition Reaction
• Reductive Elimination Reaction
• CO insertion Reaction
• Olefin Insertion Reaction and -hydride Abstraction
• Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction)
• Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
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第17週 |
6/11,6/13 |
Final Exam 13/6 |
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