課程資訊
課程名稱
 物理化學二
Physical Chemistry (Ⅱ) 
開課學期
 99-2 
授課對象
 化學工程學系  
授課教師
 戴子安 
課號
 ChemE2006 
課程識別碼
 504 26120 
班次
 01 
學分
 3 
全/半年
 半年 
必/選修
 必修 
上課時間
 星期一3,4(10:20~12:10)星期四2(9:10~10:00) 
上課地點
 普406普202 
備註
 按上學期班別選班。
限本系所學生(含輔系、雙修生)
總人數上限：63人 
Ceiba 課程網頁
 http://ceiba.ntu.edu.tw/992PChem2 
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課程概述

介紹電解質溶液、電化學與電池、化學反應動力、表面化學、膠體界面科學等之基本物性，以及液相與固相的結構特徵。
 

課程目標
 1. 了解電解質溶液的物性
2. 了解電化學與電池的基本物性
3. 了解化學反應動力
4. 了解表面化學的基礎性質
5. 了解膠體界面科學的特性
6. 了解液相與固相的結構特徵
 
課程要求
 課程大綱 分配時數 備註
單元主題 內容綱要 講授 示範 習作 其他2
Solution of electrolytes
1. Strong and weak electrolytes
2. Ion mobility and molar conductivity
3. The Debye-Huckel theory
4. Activity of ions
12 Electrochemical cells
1. Standard electrodes
2. Nernst equation
3. Thermodynamics of cells
4. Liquid-junction potential
5. Electrochemical cells
12 Chemical kinetics
1. Rate laws
2. Reaction rate constants
3. Hard-sphere collision theory
4. Transition state theory
5. Composite reactions
6. Catalysis and enzyme
14 Surface chemistry and colloids
1. Adsorption and adsorption isotherm
2. Surface tension and capillarity
3. Thermodynamics of interfaces
4. Contact angle and wettability
5. Colloids
12 Structure of matters
1. The liquid state
2. The solid state
 
預期每週課後學習時數
  
Office Hours
  
指定閱讀
 教科書1
Physical Chemistry, 4th Edition, R. J. Silbey, R. A. Alberty, and M. G. Bawendi, John Wiley & Sons, Inc., New York, 2005. 
參考書目
 Reference books:
1. Atkins’ Physical Chemistry, 8th Edition, by Atkins and de Paula, Oxford University Press.
2. Physical Chemistry, by Engel and Reid, Pearson Publishing.  
評量方式
(僅供參考)
    
課程進度
週次
日期
單元主題
第1週
   2/22: 6.9 Effect of Surface Tension on the Vapor Pressure 2/25: 6.10 Special Topic: Thermodynamics of Mxing 
第2週
   3/1: Chapter 7 Eelectrochemical Equilibrium 7.1 Coulomb's Law, Electric Field and Electric Potential 7.2 Equilibra Involving Potential Differences 7.3 Equation for an Electrochemical Cell 3/4: 7.4 Activity of Electrolytes 
第3週
   3/08: 7.5 Debye-Huckel Theory 7.6 Determination of Standard Thermodynamic Properties of Ions 7.7 Standard Electrode Potentials 3/11: 7.8 Determination of pH 
第4週
   3/15: Class in Recess 3/18 7.9 Special Topic: Commonly Used Batteries and Fuel Cells, 7.10 Membrane Potential 
第5週
   3/22 Chapter 17 17.1 Probability Density for Molecular Speeds of Gas molecules 17.2 Velocity Distribution in One Direction 17.3 Maxwell Distribution of Speeds 17.4 Types of Average Speeds 17.5 Pressure of an Ideal Gas 17.6 Collisions with a Surface and Effusion 17.7 Collision of Hard-Sphere Molecules 3/25: 17.8 Effects of Molecular Interactions on Collisions 
第6週
   3/29: 17.9 Special Topic: Transport Phenomena in Gases 17.10 Special Topic: Calculation of Transport Coefficients Chapter 18 Experimental Kinetics and Gas Reactions 18.1 Rate of Reaction 4/01:18.2 Order of Reaction  
第7週
   4/05: Class in Recess 4/08: 18.3 Reversible First-Order Reactions 18.4 Consecutive 1st Order Reactions 
第8週
   4/12: 1st Exam 4/15: 18.5 Microscopic Reversibility and Detailed Balance 18.6 Effect of Temperature 
第9週
   4/19: 18.7 Mechanism of Chemical Reactions 18.8 Relation Between rate Constants for the Forward and Backward Reactions 18.9 Bimolecular Reactions 4/22: 18.10 Unimolecular and Trimolecular Reactions 18.11 Unbranched Chain Reactions 
第10週
   4/26: Branched Chain Reactions Chapter 19 Chemical Dynamics and Photochemistry 19.1 Simple Collision Theory of Bimolecular Reactions 19.2 Potential Energy Surface 4/29: 19.3 Theoretical Calculation of a Rate Constant 
第11週
   5/03: 19.4 Transition State Theory 19.5 Principle of Photochemistry 5/06: 19.7-1 Rate of Intramolecular Process and Intermolecular Energy Transfer 
第12週
   5/10: 19.7-2 Singlet and Triplet States, fluorescence, phosphorescence, 5/13: Forster Resonance Energy Transfer (FRET)  
第13週
   5/17 2nd Exam 5/20: 19.9 The Ozone Layter in Stratosphere Chapter 20 Kinetics in the Liquid Phase 20.1 Viscosity of a Liquid 20.2 Diffusion and Sedimentation 
第14週
   5/24: 20.3 Conductivities of Electrolyte Solutions 20.4 Solvent Cage and Diffusion-Control Reaction 5/27: Class Recess 
第15週
   5/31: 20.6 Relaxation 6/03: 20.7 Acid and Base Catalysis 
第16週
   6/07: 20.8 Primary Kinetic Salt Effect 20.10 Enzyme Catalysis 20.11 Oscillating Chemical Reactions. 6/10: 21.5 Special Topic-Polymerization Kinetics  
第17週
   6/14: Chapter 24 Surface Dynamics 24.1 Physisorption and Chemisorption 24.2 Langmuir Adsorption Isotherm 24.3 Use of Adsorption Measurements to Determine Surface Area 6/17: 24.8 Heterogeneous Catalysis