課程名稱 |
膠體與界面現象 Colloid and Interfacial Phenomena |
開課學期 |
105-1 |
授課對象 |
學程 奈米科技學程 |
授課教師 |
葛煥彰 |
課號 |
ChemE7002 |
課程識別碼 |
524 M0160 |
班次 |
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學分 |
3 |
全/半年 |
半年 |
必/選修 |
選修 |
上課時間 |
星期四7,8,9(14:20~17:20) |
上課地點 |
化工一 |
備註 |
總人數上限:40人 |
Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1051ChemE7002Colloid |
課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
課程大綱
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課程概述 |
介紹膠體與界面現象基本原理,並深入探討其中與化學工程相關之課題。
General Course Description: introduction to the basic principles of colloid and interface science and discussion of their applications in the field of chemical engineering
Outline
1. Introduction to Colloidal Dispersions
--- structure of colloids
--- sedimentation equilibrium
--- Brownian motion / Einstein’s equation
2. Flocculation
--- rapid Brownian flocculation
--- slow flocculation
--- flocculants
3. Surface Energy and Surface Tension
--- surface thermodynamics
--- curvature effects / Laplace’s equation
--- surface tension measurements
--- surface tension of solutions / Gibbs adsorption equation
4. Adsorption
--- adsorption isotherms / Langmuir and BET isotherms
--- equation of state of adsorbed film
5. Osmotic Pressure of Colloidal Solutions
--- virial expansion / McMillan-Mayer theory
--- Donnan effect / colloidal electrolytes
6. Electric Double Layer
--- structure of double layer
--- Nernst-Planck equation
--- electrostatics of continua / Poisson’s equation
--- Debye-Hückel theory
--- Gouy-Chapman model
--- boundary condition at a charged interface
--- double layer interactions between bodies
--- DLVO theory
7. Electrokinetic Phenomena
--- electrophoresis, electro-osmosis
--- migration potential, streaming potential
8. Hydrodynamics of Single Particles
--- Stokes flow / Faxen’s law
--- mobility for non-spherical, rigid particles
--- sedimentation rate
9. Hydrodynamic Interactions among Particles
--- Oseen tensor
--- two-particle motions
10. Suspension Rheology
--- intrinsic viscosity
--- concentration effects on viscosity
11. Solutions of Surfactants
--- classification of surfactants
--- aggregates of surfactant molecules
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課程目標 |
1. 使學生能了解膠體與界面現象的基本原理
2. 使學生熟悉膠體與界面現象領域中與化學工程相關之課題
Course Objectives:to teach the students to
1. understand the basic principles of colloid and interface science
2. be familiar with the applications of colloid and interface science in the field of chemical engineering
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課程要求 |
先修科目或先備能力: 物理化學、輸送現象
Prerequisites:Physical Chemistry, Transport Phenomena |
預期每週課後學習時數 |
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Office Hours |
另約時間 |
指定閱讀 |
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參考書目 |
1. Adamson, A. W. and Gast, A. P., “Physical Chemistry of Surfaces”, 6th ed. (1997).
2. Berg, J. C., “An Introduction to Interfaces and Colloids”, World Scientific (2010).
3. Hiemenz, P. C. and Rajagopalan, R., “Principles of Colloid and Surface Chemistry”, 3rd ed. (1997).
4. Hunter, R. J., “Foundations of Colloid Science, Vols. I and II”, 2nd ed. (2001).
5. Lyklema, J., “Fundamentals of Interface and Colloid Science, Vols. I-V” (1991-2005).
6. Masliyah, J. H. and Bhattacharjee, S., “Electrokinetic and Colloid Transport Phenomena” (2006).
7. Newman, J. S., “Electrochemical Systems”, 2nd ed. (1991); 3rd ed. (2004, with Thomas-Alyea).
8. Rosen, M. J., “Surfactants and Interfacial Phenomena”, 3rd ed. (2004). |
評量方式 (僅供參考) |
No. |
項目 |
百分比 |
說明 |
1. |
學期考試 (Final Exam) |
50% |
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2. |
平時作業 (Homework) |
50% |
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週次 |
日期 |
單元主題 |
第1週 |
9/15 |
(National holiday on 9/15) |
第2週 |
9/22 |
1. Introduction to Colloidal Dispersions
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第3週 |
9/29 |
1. Introduction to Colloidal Dispersions
2. Flocculation
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第4週 |
10/06 |
2. Flocculation
3. Surface Energy and Surface Tension
(Homework Chapter 1 due on 10/06) |
第5週 |
10/13 |
3. Surface Energy and Surface Tension
(Homework Chapter 2 due on 10/13)
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第6週 |
10/20 |
3. Surface Energy and Surface Tension
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第7週 |
10/27 |
3. Surface Energy and Surface Tension
4. Adsorption
(Homework Chapter 3 due on 10/27) |
第8週 |
11/03 |
5. Osmotic Pressure of Colloidal Solutions
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第9週 |
11/10 |
5. Osmotic Pressure of Colloidal Solutions
6. Electric Double Layer
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第10週 |
11/17 |
6. Electric Double Layer
(Homework Chapter 5 due on 10/17) |
第11週 |
11/24 |
6. Electric Double Layer |
第12週 |
12/01 |
6. Electric Double Layer
(Homework Chapter 6 due on 12/01)
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第13週 |
12/08 |
6. Electric Double Layer
7. Electrokinetic Phenomena |
第14週 |
12/15 |
7. Electrokinetic Phenomena
8. Hydrodynamics of Single Particles
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第15週 |
12/22 |
8. Hydrodynamics of Single Particles
9. Hydrodynamic Interactions among Particles |
第16週 |
12/29 |
9. Hydrodynamic Interactions among Particles
10. Suspension Rheology
(Homework Chapter 8 due on 12/29)
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第17週 |
1/05 |
10. Suspension Rheology
11. Solutions of Surfactants
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第18週 |
1/12 |
Final Exam |
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